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Glass‐Catalyzed hydrolysis of silane coupling agents
Author(s) -
Daley L. R.,
Rodriguez F.
Publication year - 1969
Publication title -
polymer engineering and science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.503
H-Index - 111
eISSN - 1548-2634
pISSN - 0032-3888
DOI - 10.1002/pen.760090609
Subject(s) - hydrolysis , silanes , silane , catalysis , materials science , alkoxy group , chemical engineering , glass fiber , methanol , coupling (piping) , organic chemistry , polymer chemistry , composite material , chemistry , alkyl , engineering
Silane coupling agents containing organo‐functional and alkoxy groups are applied to glass fiber reinforcements from an acid solution commercially. It is found that finely divided soda glass suspended in a methanol‐water solution of various silanes promotes hydrolysis without the presence of an acid catalyst. When acid is present in addition to the glass, as in commercial application baths, rate of hydrolysis is lower than with either acid or glass alone. There is evidence that basic glass components catalyze hydrolysis. Further work under commercial application conditions is indicated.