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Rheological behavior of poly(vinyl chloride) mixture. II. Elastic behavior
Author(s) -
Sieglaff C. L.,
Vinson C. G.
Publication year - 1969
Publication title -
polymer engineering and science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.503
H-Index - 111
eISSN - 1548-2634
pISSN - 0032-3888
DOI - 10.1002/pen.760090110
Subject(s) - materials science , rheology , rheometer , composite material , viscosity , viscous flow , polymer , viscous liquid , thermodynamics , mechanics , physics
This study was undertaken in order to understand the effect of low molecular weight additives on the visco‐elastic properties of polymers and, in particular, Diamond Shamrock Corporation's PVC‐40 resin. The viscous response has been reported in Part I of this series (11). This report describes the elastic properties of these mixtures. A new theoretical analysis of elastic response has been formulated. The direct calculation of stored elastic energy from capillary rheometer measurements is now possible. The conclusion drawn from both the viscous and elastic response study is that a change in viscosity is not a necessary nor sufficient condition for improved processability. Increased flow is obtained by lowering the viscous losses, but the melt fracture phenomena may be unchanged. In order to completely characterize the compound, both viscous and elastic response must be measured.