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Fireproofing of polymers with derivatives of phosphines and with halogen‐phosphorus compounds
Author(s) -
Boyer N. E.,
Vajda A. E.
Publication year - 1964
Publication title -
polymer engineering and science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.503
H-Index - 111
eISSN - 1548-2634
pISSN - 0032-3888
DOI - 10.1002/pen.760040111
Subject(s) - fireproofing , phosphine , phosphonium , halogen , organic chemistry , phosphorus , materials science , polymer , fire retardant , polymer chemistry , chemistry , alkyl , catalysis , composite material
Chemical structures limited to phosphines and their derivatives, including phosphine oxides, phosphonium salts and halogen‐phosphorus compounds useful for fireproofing are discussed. In addition to these P‐C bond containing compounds, structures containing P‐O‐C bonds are mentioned only if they are directly formed from halophosphorus substances. The general approaches to fireproofing are described. They include physical changes, unreactive additives, reactive comonomers, substitution of other functional groups and addition to a preformed polymer. Much of the literature is reviewed and the commercial importance of certain methods for both cloth and plastics are indicated.