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Rheological properties of UHMWPE/HDPE blend gels and morphology and mechanical properties of gel‐spun fibers
Author(s) -
Yang Wenxiao,
Bin Yuezhen,
Wang Hai,
Ge Zhonghui
Publication year - 2021
Publication title -
polymer engineering and science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.503
H-Index - 111
eISSN - 1548-2634
pISSN - 0032-3888
DOI - 10.1002/pen.25740
Subject(s) - materials science , ultimate tensile strength , composite material , rheology , polyethylene , high density polyethylene , ultra high molecular weight polyethylene , morphology (biology) , elongation , fiber , spinning , genetics , biology
To produce polyethylene (PE) fibers with relatively high tensile strength but low cost, ultra‐high‐molecular‐weight polyethylene (UHMWPE)/high‐density polyethylene (HDPE) (UH) blend gels were prepared from paraffin oil and further fabricated into UH blend fibers by gel spinning. This research focused on the rheological properties of UH blend gels with high solid contents (SCs) ranging from 25 to 100 g/L, as well as morphology and mechanical properties of resultant gel‐spun UH blend fibers. The rheological measurements indicated that the apparent viscosity, shear storage, and loss moduli of the UH blend gels were not markedly increased compared with those of the UHMWPE gel with much less SC. No obvious solid–liquid phase separation occurred in UH blend gels at a temperature above the sol–gel transition temperature. UH blend fibers were prepared by drawing as‐spun fibers (draw ratio [ λ ] = 3) at 110°C to λ = 15, 45, 60, and 80, respectively. The orientation degree of fibril structure in UH blend fibers increased with increasing λ but the length of fibrils ( L fibril ) showed a complex change. The L fibril of UH blend fibers became larger due to chain arrangement in company with the transformation of the kebab structure to the extended shish structure when the λ was less than 45 but decreased during further elongation ( λ = 60 and 80) because of fibril breakage and recrystallization. The change in morphological behavior led to the corresponding change in mechanical properties of resultant gel‐spun UH blend fibers. The tensile strength of gel‐spun UH55‐45 blend fiber (UHMWPE/HDPE = 5/5 and λ = 45) reached 15.6 cN/dtex, which could fulfill the requirement of mechanical properties in common application.