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The Potential Use of Epoxy‐POSS as a Reactive Hybrid Compatibilizers for PLA/PBAT Blends: “Effect of PBAT Molecular Weight and POSS Type”
Author(s) -
Kilic Nilay Tuccar,
Can Buse Nur,
Kodal Mehmet,
Ozkoc Guralp
Publication year - 2020
Publication title -
polymer engineering and science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.503
H-Index - 111
eISSN - 1548-2634
pISSN - 0032-3888
DOI - 10.1002/pen.25295
Subject(s) - epoxy , materials science , composite material , glass transition , rheology , compatibilization , thermal stability , polymer blend , chemical engineering , polymer , copolymer , engineering
This article focuses on the effect of molecular weight of poly(butylene adipate‐co‐terephthalate) (PBAT) on the immiscible poly(lactic acid) (PLA)/PBAT blends compatibilized with epoxidized polyhedral oligomeric silsesquioxanes (Epoxy‐POSSs) having different numbers of epoxy groups per molecule. Mechanical, thermomechanical, thermal, rheological, and morphological properties of the blends were investigated as a function of PBAT molecular weight and epoxy‐POSS type. Mechanical tests revealed that all epoxy‐POSS types significantly improved the performance of the blends containing low‐molecular‐weight PBAT. On the other hand, epoxy‐POSS with three epoxy functional groups (TriEpPOSS) and Epoxy‐POSS with multiple‐epoxy functional groups (MuEpPOSS) only slightly improved the performance of blends with high‐molecular‐weight PBAT. Thermomechanical and thermal test results supported that the compatibilization effects of the epoxy‐POSSs were more prominent in the PLA/PBAT blends with low‐molecular‐weight PBAT due to the observation of the shifts in the glass transition temperatures of the PLA phase. According to the rheological results, the addition of epoxy‐POSSs increased the interactions between the PLA and PBAT phases much more effectively in the PLA/PBAT with low‐molecular‐weight PBAT. The dispersed phase size of the PBAT further decreased in the low‐molecular‐weight PLA/PBAT blend system due to the enhanced compatibility much better. POLYM. ENG. SCI., 60: 398–413, 2019. © 2019 Society of Plastics Engineers