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Effect of clay amount and reprocessing cycles on thermal, morphological, and mechanical properties of polypropylene/organovermiculite nanocomposites
Author(s) -
Araújo Elvis A. F.,
Visconte Leila L. Y.,
da Silva Ana L. N.,
Sirelli Lys,
Pacheco Élen B. A.V.
Publication year - 2019
Publication title -
polymer engineering and science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.503
H-Index - 111
eISSN - 1548-2634
pISSN - 0032-3888
DOI - 10.1002/pen.25213
Subject(s) - polypropylene , materials science , exfoliation joint , melt flow index , nanocomposite , maleic anhydride , ultimate tensile strength , thermal stability , composite material , flexural strength , dispersion (optics) , izod impact strength test , extrusion , polymer , chemical engineering , copolymer , graphene , physics , optics , engineering , nanotechnology
Nanocomposites of polypropylene (PP) and PP‐grafted‐maleic anhydride (PP‐ g ‐MA) with and without organophilic vermiculite (OVMT) (5–8%w/w) were evaluated. The nanocomposites and neat PP were submitted to extrusion reprocessing cycles. It was found that the presence of OVMT in PP/PP‐ g ‐MA was critical for maintaining thermal stability during reprocessing. The exfoliation/intercalation was confirmed, mainly, in the nanocomposite submitted to reprocessing cycles, by X‐ray diffraction. The melt flow index (MFI) values for the 3× and 5× reprocessed PP increased by 40% and 70%, respectively, as compared to the neat PP. The MFI for the 3× and 5× reprocessed PP/PP‐ g ‐MA/OVMT decreased 26% and 17%, respectively, as compared to the decrease occurred in the 3× and 5× reprocessed PP, indicating that the presence of 5% (w/w) OVMT was sufficient to allow an increase in viscosity. The reprocessed nanocomposites exhibited values for tensile and flexural strengths and Izod impact, in general, greater than or near to those of PP with the same number of reprocessing cycles. The increase or maintenance of mechanical properties seems to depend on a balance between the extent of intercalation/exfoliation and dispersion of OVMT in the PP matrix, and the degree of degradation of the PP matrix. POLYM. ENG. SCI., 59:2110–2120, 2019. © 2019 Society of Plastics Engineers