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Isothermal crystallization kinetics of biodegradable poly(lactic acid)/poly(ε‐caprolactone) blends compatibilized with low‐molecular weight block copolymers
Author(s) -
Pereira Fabiana Massarente,
Canevarolo Sebastião Vicente,
Chinelatto Marcelo Aparecido
Publication year - 2019
Publication title -
polymer engineering and science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.503
H-Index - 111
eISSN - 1548-2634
pISSN - 0032-3888
DOI - 10.1002/pen.25019
Subject(s) - materials science , crystallization , caprolactone , crystallinity , compatibilization , polymer chemistry , nucleation , chemical engineering , copolymer , differential scanning calorimetry , polycarbonate , spherulite (polymer physics) , kinetics , avrami equation , polymer blend , polymer , composite material , crystallization of polymers , organic chemistry , chemistry , thermodynamics , physics , quantum mechanics , engineering
The isothermal crystallization kinetics of biodegradable blends made of poly(lactic acid) (PLA) and poly(ε‐caprolactone) (PCL) compatibilized with two different low molecular weight block copolymers, that is, ε‐caprolactone/tetramethylene ether glycol and ε‐caprolactone/aliphatic polycarbonate (CB), was done. Blends were prepared by melt mixing in an extruder, while isothermal crystallization kinetics and morphologies were investigated by thermal (differential scanning calorimetry) and thermo‐optical (quantitative polarized light optical microscopy [qPLOM]) quantitative methods. Data were analyzed using the Avrami equation, revealing 2D and 3D growth and simultaneous heterogeneous nucleation. The presence of low molecular weight compatibilizers, that is, 2,000 g mol −1 , accelerated the PLA crystallization rate by two to threefold when compared with neat PLA, with high degrees of crystallinity (40–43%) as confirmed by PLOM images. The activation energy ( E a ) showed that PCL inhibits PLA crystallization; however, the addition of block copolymers used as compatibilizers of the blends reduced E a values, increasing the chain mobility of PLA and thus increasing the crystallization rate. POLYM. ENG. SCI., 59:E161–E169, 2019. © 2018 Society of Plastics Engineers