Physical coloring of multilayered polymeric structures

Multilayered polymer structures made of two transparent, hyperelastic thermoplastic polyurethanes (TPUs) have been studied. The sheets, made by co‐extrusion and layer multiplication techniques, exhibited “physical coloring”, where a preferred wavelength range was reflected and visualized, due to the refractive index difference and nanometric thicknesses of the alternating layers. The extrusion system comprises two extruders and a series of multiplying units, each doubling the number of layers, such that 12 multiplying units render 2 12 + 1 +1 (= 8,193) layers. For a 0.8 mm‐thick die, the resulting layers after die swell are ∼ 150 nm thick. The extrusion temperatures of both grades were adjusted to equilibrate the viscosities and thus stabilize the layers. TPUs are highly elastic, and large stretching ratios allow for significant reduction in thickness. Physical coloring developed in a controlled, reversible manner. The visual color correlates with elongation, and can be offset by choice of initial thickness. Both reflected and transmitted wavelengths change throughout the whole visible range. A model was developed to fit the reflectance data, by introducing a “stress–volume coefficient” due to volume changes during stretch. This model fits the data very well. Characterization by AFM and TEM showed few discontinuous layers and some defects in the structure, nevertheless the multilayer structure is demonstrated. POLYM. ENG. SCI., 59:112–119, 2019. © 2018 Society of Plastics Engineers