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Dispersive mixing efficiency of an elongational flow mixer on PP/EPDM blends: Morphological analysis and correlation with viscoelastic properties
Author(s) -
Rondin Jérôme,
Bouquey Michel,
Muller René,
Serra Christophe A.,
Martin Grégory,
Sonntag Philippe
Publication year - 2014
Publication title -
polymer engineering and science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.503
H-Index - 111
eISSN - 1548-2634
pISSN - 0032-3888
DOI - 10.1002/pen.23667
Subject(s) - materials science , composite material , polypropylene , viscoelasticity , rheology , mixing (physics) , ethylene propylene rubber , polymer blend , dispersion (optics) , viscosity , phase (matter) , copolymer , polymer , chemistry , organic chemistry , optics , physics , quantum mechanics
Polypropylene and ethylene‐propylene‐diene terpolymer (PP/EPDM) blends were melt compounded in a new mixing device, designed in our laboratory under the trademark of RMX®, which predominantly generates elongational flows. Dispersion of the EPDM minor phase in PP was carried out in both RMX® and in an internal mixer (Haake Rheomix 600) at equivalent specific mixing energies and the resultant morphologies obtained by SEM were analyzed and compared. A better dispersive mixing efficiency of the RMX® mixer, i.e., lower D n and D v of the dispersed EPDM phase was observed. The impact of elongational flow was more pronounced for blends having a high viscosity ratio p , indicating an enhanced droplet break‐up mechanism, which was attributed to the combination of high shear rates inside the mixing element and important elongational flows in the convergent/divergent zones. The morphology of the blends was correlated with their linear viscoelastic properties by using the Palierne model. Very good agreement was found for the PP/EPDM 80/20 blends but for higher EPDM content, the Palierne model failed to describe the rheological behavior, which was attributed to percolation of the minor phase with increasing the concentration. Higher elasticity at low frequencies was observed for blends processed in the RMX®, which was attributed to a higher generated interfacial area. POLYM. ENG. SCI., 54:1444–1457, 2014. © 2013 Society of Plastics Engineers