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Filler exfoliation and dispersion in polypropylene/as‐received graphite nanocomposites via cryogenic milling
Author(s) -
Hubert Paul J.,
Kathiresan Krishna,
Wakabayashi Katsuyuki
Publication year - 2011
Publication title -
polymer engineering and science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.503
H-Index - 111
eISSN - 1548-2634
pISSN - 0032-3888
DOI - 10.1002/pen.22001
Subject(s) - materials science , polypropylene , composite material , exfoliation joint , graphite , nanocomposite , percolation threshold , thermal stability , polymer , thermal conductivity , electrical resistivity and conductivity , graphene , chemical engineering , nanotechnology , engineering , electrical engineering
Abstract Nanocomposites from polypropylene and unmodified, as‐received graphite were fabricated via solid‐state cryogenic milling (cryomilling) process. Filler contents up to 10 wt% were studied with cryomilling cycles and postcryomill melt mixing option as processing parameters. Scanning electron microscopy and X‐ray diffraction of the cryomilled samples reveal that graphite filler particles are partially exfoliated into nanoplatelets, as well as fragmented in the lateral dimensions, when incorporated into the polymer matrix. Various physical performance, including polymer crystallization rate, thermomechanical response, oxygen barrier, and electrical conductivity, is closely dictated by the filler morphology. An increase in cryomilling time leads to a higher degree of exfoliation, resulting in an enhancement in stiffness/strength, thermal stability, and electrical conductivity. Postcryomill melt mixing disperses the partially exfoliated graphite nanoplatelets, raising stiffness/strength and thermal stability while reducing electrical conductivity and oxygen permeability. The percolation threshold occurs between 1 and 3 wt%, with an optimum content for most properties at ∼3 wt%. POLYM. ENG. SCI., 2011. © 2011 Society of Plastics Engineers