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Linear viscoelasticity, probe tack, and extrusion flow results of SEBS copolymers
Author(s) -
Arevalillo Alfonso,
Fernández Mercedes,
Muñoz María Eugenia,
Santamaría Anton
Publication year - 2010
Publication title -
polymer engineering and science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.503
H-Index - 111
eISSN - 1548-2634
pISSN - 0032-3888
DOI - 10.1002/pen.21667
Subject(s) - materials science , viscoelasticity , extrusion , polystyrene , copolymer , capillary action , composite material , adhesion , polymer , relaxation (psychology) , flow (mathematics) , polymer chemistry , mechanics , psychology , social psychology , physics
Microphase‐separated poly(styrene‐b‐ethylene‐co‐butylene‐ b‐styrene) copolymers of different molecular weights with polystyrene (PS) volume fraction ϕ = 0.30 are investigated. Linear dynamic viscoelastic data reveal the blocking effect of the ordered PS microdomains, which produces a predominantly elastic response at low frequencies, associated with a mechanical relaxation. These results are correlated with tack and extrusion flow measurements, which involve polymer/metal adhesion processes. Nonlinearity implied in some experiments alters the ordered morphology of low molecular weight samples producing a viscous dominant behavior. Dissipation is reflected in viscous‐like adhesion and lack of viscoplastic response in extrusion flow experiments. For the highest molecular sample, only a rubbery or entangled state (G′ > G″ and G′ > 10 5 Pa) is observed in the linear viscoleastic regime. This is associated with the lack of adhesion seen in both, probe tack experiments and capillary flow measurements. This lack of adhesion gives rise to a plug‐flow as the polymer slips in the capillary wall. POLYM. ENG. SCI., 2010. © 2010 Society of Plastics Engineers