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Cell coalescence suppressed by crosslinking structure in polypropylene microcellular foaming
Author(s) -
Zhai Wentao,
Wang Hongying,
Yu Jian,
Dong Jinyong,
He Jiasong
Publication year - 2008
Publication title -
polymer engineering and science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.503
H-Index - 111
eISSN - 1548-2634
pISSN - 0032-3888
DOI - 10.1002/pen.21095
Subject(s) - polypropylene , materials science , coalescence (physics) , blowing agent , cell size , copolymer , cell structure , composite material , supercritical fluid , chemical engineering , polymer chemistry , polymer , polyurethane , organic chemistry , chemistry , physics , engineering , astrobiology , biological system , biology , microbiology and biotechnology
A series of crosslinked polypropylene samples with increased melt strengths were prepared via a copolymerization reaction, followed by melt processing. These crosslinked PP samples (PP‐Cs) were foamed by a temperature rising process using supercritical CO 2 as the physical blowing agent. The introduction of crosslinking structure resulted in PP‐Cs foams with well‐defined closed cell structure, decreased cell size, and increased cell density in comparison with a linear PP, which were attributed to the suppressed cell coalescence due to the significant increase in melt strength of PP‐Cs. Further increasing the crosslinking degree tended to enhance the suppression effect on the cell coalescence, and hence increase the cell density of PP foams under the same foaming conditions, especially at the longer foaming times. The well‐defined closed cell structure was observed at the foaming temperature of 170–250°C and saturation pressure of 12–20 MPa. POLYM. ENG. SCI., 2008. © 2008 Society of Plastics Engineers