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PAN based quasi carbon whiskers reinforced PI polyblends: Microhardness, mechanical, hydraulic, and morphological study
Author(s) -
Kurmvanshi S.K.,
Gupta A.K.,
Patel P.R.,
Bajpai R.,
Keller J.M.
Publication year - 2008
Publication title -
polymer engineering and science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.503
H-Index - 111
eISSN - 1548-2634
pISSN - 0032-3888
DOI - 10.1002/pen.20976
Subject(s) - materials science , whiskers , indentation hardness , polyimide , composite material , polyacrylonitrile , morphology (biology) , layer (electronics) , polymer , microstructure , biology , genetics
Polyimide (PI)/Polyacrylonitrile (PAN) polyblend films were prepared using solution cast technique by spin coating unit. PAN was incorporated within the PI matrix in different concentration i.e. 10 −3 , 10 −2 , 10 −1 , and 1 wt% to prepare polyblend films. The PI polyblend film incorporated with 10 −1 wt% PAN and cured at 330°C produces well defined quasi carbon whiskers within the PI matrix. Evidence of the orientation of these carbon whiskers was indicated by optical microscopy and AFM. The improved microhardness, mechanical performance, and hydraulic resistivity of 10 −1 wt% PI/PAN polyblend film was observed and attributed to the orientation of these partially carbonized whiskers within PI matrix. The overall property decreases with increasing the concentration of PAN over 10 −1 wt%. The incorporation of ultra low concentration of PAN within the PI provides means of achieving excellent combination of microhardness, mechanical, and hydraulic resistance with improved morphology. POLYM. ENG. SCI., 2008. © 2008 Society of Plastics Engineers