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Fullerene‐functionalized polycarbonate: Synthesis under microwave irradiation and nonlinear optical property
Author(s) -
Wu Huixia,
Li Feng,
Lin Yanghui,
Cai Ruifang,
Tong Rui,
Qian Shixiong
Publication year - 2006
Publication title -
polymer engineering and science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.503
H-Index - 111
eISSN - 1548-2634
pISSN - 0032-3888
DOI - 10.1002/pen.20491
Subject(s) - polycarbonate , materials science , fullerene , polymer , solvent , gel permeation chromatography , chloroform , benzophenone , fourier transform infrared spectroscopy , polymer chemistry , organic chemistry , chemical engineering , chemistry , composite material , engineering
Fullerenation of polycarbonate (PC), a commercially important optical polymer, was achieved by direct reaction of C 60 and PC in the presence of azo‐bis‐isobutyronitrile (AIBN), using 1,1,2,2‐tetrachloroethane as the solvent under microwave irradiation (MI). Compared with conventional heating process, MI could significantly enhance the rate of the fullerenation under identical reaction conditions. The C 60 content of the fullerene‐functionalized polycarbonate (C 60 ‐PC) could be controlled via varying the C 60 /PC feed ratio and the reaction time. The C 60 ‐PCs are soluble in common organic solvents such as THF and chloroform. The products were characterized by gel permeation chromatography, UV–vis, FTIR, TGA, DSC, 1 H NMR, and 13 C NMR. The reaction of C 60 with PC under MI was monitored by electron spin resonance spectra, the fullerene radicals were detected in reaction solutions and also in the solid product polymers, indicating the radical mechanism of the reaction. The nonlinear optical property of C 60 ‐PCs in THF was investigated by the open‐aperture z ‐scan technique at 527 nm, and its nonlinear absorption coefficient was found to be in the same order as that of C 60 . POLYM. ENG. SCI., 46:399–405, 2006. © 2006 Society of Plastics Engineers