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Study of kinematics and dynamics of film blowing of different polyethylenes
Author(s) -
GhanehFard A.,
Carreau P. J.,
Lafleur P. G.
Publication year - 1997
Publication title -
polymer engineering and science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.503
H-Index - 111
eISSN - 1548-2634
pISSN - 0032-3888
DOI - 10.1002/pen.11759
Subject(s) - low density polyethylene , materials science , linear low density polyethylene , composite material , polyethylene , viscosity , polymer , high density polyethylene , bubble , flow birefringence , strain rate , birefringence , mechanics , optics , physics
An extensive experimental study of the effects of material characteristics and processing parameters on the kinematics and dynamics of film blowing is presented. Three polyethylene resins, a high‐density polyethylene (HDPE), a low‐density polyethylene (LDPE), and a linear low‐density polyethylene (LLDPE) were investigated. The convergent flow analysis of Cogswell was used to characterize the elongational flow behavior of the polymers. Strain rates and pressure inside the bubble ( P i ) have been determined over a wide range of film blowing conditions. Moreover, on‐line bubble temperature and birefringence measurements have been carried out along the length of the bubble. The experimental results reveal that the three polymers display different behaviors. The LLDPE requires the highest P i value and the LDPE, the lowest. Consistent with this, the LLDPE shows the lowest in‐plane birefringence and the LDPE, the highest. Interactions between various process parameters affecting the P i value are characterized. Bubble instability is correlated to the apparent uniaxial elongational viscosity and P i . The most stable polymer (LDPE) has the highest elongational viscosity and requires the lowest P i . Stresses have been calculated with the help of the birefringence and P i data. The stress and strain rate data were used to calculate an apparent nonuniform biaxial elongational viscosity of the melts, but could not be correlated through any simple constitutive equation.