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Thermal analysis of vectra B950 liquid crystal polymer
Author(s) -
Chung TaiShung,
Cheng Min,
Pallathadka P. K.,
Goh Suat Hong
Publication year - 1999
Publication title -
polymer engineering and science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.503
H-Index - 111
eISSN - 1548-2634
pISSN - 0032-3888
DOI - 10.1002/pen.11484
Subject(s) - materials science , crystallization , differential scanning calorimetry , thermal decomposition , chemical process of decomposition , decomposition , annealing (glass) , chemical engineering , isothermal process , polymer , thermogravimetric analysis , polymer chemistry , thermodynamics , organic chemistry , composite material , chemistry , physics , engineering
The melting and crystallization behavior of Vectra tm B950, a random liquid crystalline copoly(ester amide), was studied by differential scanning calorimetry (DSC). Nonisothermal experiments showed the existence of some interesting and peculiar transition behavior, which may depend on the crystallization conditions (cooling rate). In isothermal experiments, both the thermal and crystallization behavior have been studied as functions of annealing temperature and annealing time. Different thermal behaviors were observed, indicating the possibility of multiple states of mesophase aggregation In addition, the thermal decomposition of Vectra B950 was also studied by TGA‐FTIR in both nitrogen and air environments. A single‐stage decomposition process was found when heating in nitrogen atmosphere, and the decomposition is due to the easter linkage rupture. A double‐stage decomposition process was found when heating in air, and the decompositions are mainly due to the ester linkage rupture for the first decomposition step and the oxidative reaction for the second decomposition step. Annealing slightly changes the decomposition composition occuring in the early stage of thermal degradation.