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Cure monitoring of photosensitive resins by photo‐dynamic mechanical analysis
Author(s) -
Renault Thierry,
Ogale Amod A.,
Drews Mike J.
Publication year - 1996
Publication title -
polymer engineering and science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.503
H-Index - 111
eISSN - 1548-2634
pISSN - 0032-3888
DOI - 10.1002/pen.10441
Subject(s) - materials science , composite material , modulus , dynamic mechanical analysis , ultraviolet , plateau (mathematics) , elongation , ultimate tensile strength , polymer , optoelectronics , mathematical analysis , mathematics
A new technique, photo‐dynamic mechanical analysis, was developed to monitor the cure of photosensitive resins. In this technique, the resin is dispensed on a low modulus substrate and the force needed to maintain a prescribed elongation on the sample is measured while the sample is exposed to an ultraviolet source. The force increases with the extent of cure and reaches a plateau when the resin is fully cured. Photo‐dynamic mechanical analysis was found to be a rapid, continuous, and reliable technique to monitor the extent of cure of photopolymerizable resins. A finite element analysis was developed to calculate the resin modulus from the experimental force data. Thus, it was possible to monitor the resin modulus from the liquid state to the solid state.