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Mechanical behavior of injection molded β‐crystalline phase polypropylene
Author(s) -
Tjong S. C.,
Shen J. S.,
Li R. K. Y.
Publication year - 1996
Publication title -
polymer engineering and science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.503
H-Index - 111
eISSN - 1548-2634
pISSN - 0032-3888
DOI - 10.1002/pen.10390
Subject(s) - materials science , ultimate tensile strength , scanning electron microscope , spherulite (polymer physics) , izod impact strength test , composite material , polypropylene , toughness , drop (telecommunication) , elongation , phase (matter) , polymer , chemistry , organic chemistry , computer science , telecommunications
Abstract High purity and a large amount of β‐modification can be produced in polypropylene (PP) by adding a bicomponent β‐nucleator consisting of equal amounts of pimelic acid and calcium stearate. Wide angle X‐ray diffraction (WAXD), scanning electron microscopy (SEM), static tensile tests, Izod impact tests, and instrumented drop weight impact testing were used to characterize the structure, morphology, and mechanical behavior of the β‐phase PP. The WAXD patterns show that the relative content of the β‐phase (K value) in the skin layer of the injection molded specimen is 0.54, whereas the K value in the core section is 0.92. SEM observations reveal that the β‐spherulite exhibits a sheaf‐like structure and there are no clear boundaries between the spherulites. Static tensile tests indicate that the elongation at break of pure PP is enhanced by the addition of a β‐nucleator. The impact and drop weight tests also indicate that the impact resistance of PP is improved by adding the β‐nucleating agent. The improvement in impact toughness is associated with the formation of microcrazes within the PP.