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Preparation and properties of optically transparent, pressure‐cured poly(methacrylate) composites
Author(s) -
Weaver Kevin D.,
Stoffer James O.,
Day Delbert E.
Publication year - 1993
Publication title -
polymer composites
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.577
H-Index - 82
eISSN - 1548-0569
pISSN - 0272-8397
DOI - 10.1002/pc.750140609
Subject(s) - materials science , composite material , composite number , curing (chemistry) , flexural strength , glass fiber , poly(methyl methacrylate) , methacrylate , methyl methacrylate , refractive index , fiber , polymer , polymerization , optoelectronics
The objective of this work was to develop optically transparent glass fiber reinforced poly(methyl methacrylate) (PMMA) composites by matching the refractive index of the glass fiber reinforcement to that of the PMM, A matrix, thereby minimizing the quantity of light which is normally scattered and reflected at the interface of dissimilar materials. A pressure curing process is described for preparing composites 10 by 15 by 0.6 cm thick and containing up to ∼ 35% glass fiber. By curing at 65°C under 6.9 MPa N 2 for 18 H, composites have been produced with optical quality surfaces and flexural strengths more than seven times that of commercial PMMA of the same thickness. A transparent composite containing 10.4 vol% of 13 μm diameter fiber had an 84% optical transmission (92% maximum for PMMA) at 600 nm and 25°C.