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Model compound studies on the amine cure of epoxy resins
Author(s) -
Byrne Catherine A.,
Hagnauer Gary L.,
Schneider Nathan S.,
Lenz Robert W.
Publication year - 1980
Publication title -
polymer composites
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.577
H-Index - 82
eISSN - 1548-0569
pISSN - 0272-8397
DOI - 10.1002/pc.750010204
Subject(s) - epoxy , polymerization , amine gas treating , materials science , curing (chemistry) , polymer chemistry , composite material , organic chemistry , chemistry , polymer
Monoepoxy phenyl glycidyl ether, curing agent p‐chloroaniline, and the substituted urea type accelerator Monuron were used as a model system for studying the amine cure of epoxies. Reactions were carried out at 120°C with amine to epoxy equivalent rations of 0.25 and 1.0 Reaction mixtures were analyzed primarily by reverse phase high performance liquid chromatography. Three types of reactions occur; simple amine addition to epoxy, homopolymerization of epoxy, and epoxy polymerization involving the addition products. In the absence of accelerator the reaction involved simple addition. With the accelerator, there was competition between addition and polymerization, the balance depending on the amine to epoxy equivalent ratio. Both addition and polymerization were important for a ratio of 1, but polymerization far outweighed addition for a ratio of 0.25.