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Uniform fiber orientation and transcrystallization formed in isotactic polypropylene/short glass fiber composites via a shear‐induced orientation extrusion
Author(s) -
Li GuoXing,
Li Yin,
Shi YuDong,
Zhang Kai,
Zeng JianBing,
Wang Ming
Publication year - 2018
Publication title -
polymer composites
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.577
H-Index - 82
eISSN - 1548-0569
pISSN - 0272-8397
DOI - 10.1002/pc.24324
Subject(s) - materials science , composite material , extrusion , tacticity , ultimate tensile strength , crystallinity , shear (geology) , polypropylene , modulus , glass fiber , polymer , polymerization
The orientation of short glass fibers (SGFs) and the interfacial interaction between SGFs and isotactic polypropylene (iPP) matrix play main roles in the final properties of the iPP/SGFs composites. Here we show a self‐design shear‐induced orientation extrusion (SIOE) to efficiently fabricate the iPP/SGFs composites with evenly dispersion and orientation of SGFs in the whole iPP matrix. The shear stress and the orientation of SGFs are also benefit to induce transcrystals which enhance the interfacial interaction between SGFs and iPP matrix. The crystallinity in average of the iPP/5.0 wt% SGFs composites shows nearly 10% higher than that of pure iPP extruded by the SIOE system. The iPP/5.0 wt% SGFs composites extruded by high shear stress not only exhibit higher yield strength and Young's modulus than that of the composites extruded by low shear stress but also maintain high tensile strength and strain at break. The enhancement of mechanical properties is ascribed to the uniform dispersion and orientation of SGFs, high crystallinity, and high interfacial interaction between SGFs and iPP matrix induced by transcrystals. POLYM. COMPOS., 39:3168–3177, 2018. © 2017 Society of Plastics Engineers