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Carbon nanotube functionalization effects on thermal properties of multiwall carbon nanotube/polycarbonate composites
Author(s) -
ElBrolossy Tarek A.,
Ibrahim Sobhy S.,
Alkhudhayr Eman A.
Publication year - 2015
Publication title -
polymer composites
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.577
H-Index - 82
eISSN - 1548-0569
pISSN - 0272-8397
DOI - 10.1002/pc.23028
Subject(s) - materials science , carbon nanotube , composite material , thermal diffusivity , thermal effusivity , thermal conductivity , surface modification , interfacial thermal resistance , polycarbonate , thermal resistance , thermal , thermal contact conductance , chemical engineering , meteorology , engineering , physics , quantum mechanics
The thermal properties of composites based on polycarbonate (PC) filed with ultraviolet/ozone (UVO) treated multiwall carbon nanotubes (MWCNTs) in low limit (less than 0.01) volume fractions have been investigated. The composites were prepared in the form of films of relatively small thickness (23–33 μm) with random orientation of treated MWCNTs. Functionalization of MWCNTs has been confirmed through Fourier transform infrared measurements. Thermal conductivity was obtained by measuring both of thermal diffusivity and thermal effusivity using photoacoustic technique. The results reveal that the addition of UVO treated MWCNTs lead to enhance both the thermal diffusivity and thermal effusivity of the composites. Insertion of 0.95% MWCNTs into PC improves the thermal conductivity of the composites by ∼22%. This enhancement is reasonable using such low content of MWCNTs of moderate aspect ratio. The experimental results were analyzed using a simple model concerning some relevant parameters such as volume fractions, interfacial thermal resistance, aspect ratio, and nonstraightness of nanotubes. An interface thermal resistance in the low limit of about 2.1 × 10 −8 m 2 K/W has been estimated. In the light of these results, the role of MWCNTs functionalization on the overall thermal transport properties of MWCNTs‐polymer composites has been discussed. POLYM. COMPOS., 36:1242–1248, 2015. © 2014 Society of Plastics Engineers