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Structure and morphology of composites based on polyvinylidene fluoride filled with BaTiO 3 submicrometer particles: Effect of processing and filler content
Author(s) -
Olmos D.,
Montero F.,
GonzálezGaitano G.,
GonzálezBenito J.
Publication year - 2013
Publication title -
polymer composites
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.577
H-Index - 82
eISSN - 1548-0569
pISSN - 0272-8397
DOI - 10.1002/pc.22618
Subject(s) - materials science , polyvinylidene fluoride , differential scanning calorimetry , composite material , crystallization , lamellar structure , fourier transform infrared spectroscopy , scanning electron microscope , morphology (biology) , barium titanate , phase (matter) , ball mill , polymer , chemical engineering , ceramic , chemistry , physics , genetics , organic chemistry , biology , engineering , thermodynamics
Composites based on polyvinylidene fluoride filled with barium titanate (PVDF/BT) submicrometric particles were prepared. To uniformly disperse BT particles within PVDF, high‐energy ball cryomilling was used. The effect of processing and the presence of BT particles on the structure and morphology of the composites were analyzed by Fourier transformed infrared spectroscopy, X‐ray diffraction, differential scanning calorimetry, and atomic force microscopy. In terms of the structure, it can be concluded/stated that after milling the α‐ and γ‐PVDF crystalline phases are reduced, whereas the content in the β phase is increased. On the other hand, after film formation, the α phase was recovered. It was demonstrated that the milling process is the most important factor to increase the amount of β phase, being favored by the presence of BT particles. In terms of the morphology, it was observed that the PVDF lamellar aspect ratio increases with the amount of BT in cryomilled samples processed as films. Besides, the crystallization kinetics is highly affected by the milling process and the presence of BT, being the relative crystallization rate slower with the presence of BT. POLYM. COMPOS., 34:2094–2104, 2013. © 2013 Society of Plastics Engineers