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Multiwalled carbon nanotube/polysulfone composites: Using the Hildebrand solubility parameter to predict dispersion
Author(s) -
Dooher Thomas,
Dixon Dorian
Publication year - 2011
Publication title -
polymer composites
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.577
H-Index - 82
eISSN - 1548-0569
pISSN - 0272-8397
DOI - 10.1002/pc.21222
Subject(s) - materials science , carbon nanotube , polysulfone , composite material , fourier transform infrared spectroscopy , solubility , dispersion (optics) , hildebrand solubility parameter , composite number , nanocomposite , thermal stability , ultimate tensile strength , casting , chemical engineering , polymer , organic chemistry , chemistry , physics , optics , engineering
Polysulfone composites were prepared by solution casting, using various types of treated carbon nanotubes (CNTs) at loadings of up to 5 wt%. The CNT types tested were: as‐received, acid treated, OCA surfactant, OCA functionalized and Poly(methyl methacrylate) functionalized nanotubes prepared using both as‐received and acid treated CNT. The treatment types investigated were selected based upon their solubility parameters and on the results of previous studies. The treated CNTs, CNT/solvent dispersions and the final composite samples were characterised using Fourier Transform Infrared Spectroscopy (FTIR), thermal analysis, Transmission Electron Microscopy (TEM), Ultraviolet‐Visible (UV‐vis) spectroscopy, optical microscopy, electrical conductivity and tensile testing. It was observed that the all the treatments studied improved the stability of CNT in the solvent. Of the CNT types studied, composites containing OCA functionalised CNT displayed the lowest percolation threshold (3 wt%) and highest mechanical performance. While the use of Hildebrand solubility parameters is useful in indentifying promising CNT treatments, their use can not fully predict CNT dispersion behaviour and composite performance. It is also critical to consider the influence of any treatments on CNT length and residual solvent levels. POLYM. COMPOS., 2011. © 2011 Society of Plastics Engineers

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