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One‐step synthesis of highly conductive PPy/graphite nanosheets/Gd 3+ composites
Author(s) -
Mo Zunli,
Sun Wanhong,
Guo Ruibin,
Xie Tingting,
He Jingxian,
Feng Chao
Publication year - 2011
Publication title -
polymer composites
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.577
H-Index - 82
eISSN - 1548-0569
pISSN - 0272-8397
DOI - 10.1002/pc.21147
Subject(s) - materials science , graphite , polypyrrole , composite material , dopant , thermal stability , polymerization , thermogravimetric analysis , conductive polymer , in situ polymerization , chemical engineering , doping , polymer , optoelectronics , engineering
Highly conductive polypyrrole/graphite nanosheets/Gd 3+ (PPy/nanoG/Gd 3+ ) composites are fabricated via in situ polymerization using p ‐toluenesulfonic acid as a dopant and FeCl 3 as an oxidant. The effects of the graphite nanosheets and Gd 3+ loading on the electrical conductivity are investigated. The maximum conductivity of PPy/nanoG/Gd 3+ composites about 17.86 S/cm found with 3 wt% graphite nanosheets and 6 wt% Gd 3+ at room temperature. The results showed that the high‐aspect‐ratio structure of graphite nanosheets played an important role in forming a conducting network in PPy matrix. Thermal gravimetric analysis demonstrates an improved thermal stability of PPy in the PPy/nanoG/Gd 3+ composites. The microstructures of PPy/nanoG/Gd 3+ are evidenced by the SEM and TEM examinations. POLYM. COMPOS., © 2011 Society of Plastics Engineers.