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LDPE/EVA/PCR/MWNT nanocomposites: Radiation crosslinking and physicomechanical characteristics
Author(s) -
Dubey Kumar Abhinav,
Bhardwaj Yatender K.,
Chaudhari Chandrashekhar V.,
Sabharwal Sunil
Publication year - 2011
Publication title -
polymer composites
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.577
H-Index - 82
eISSN - 1548-0569
pISSN - 0272-8397
DOI - 10.1002/pc.21092
Subject(s) - materials science , low density polyethylene , nanocomposite , composite material , melt flow index , carbon nanotube , nucleation , polyethylene , elongation , polymer , ultimate tensile strength , copolymer , chemistry , organic chemistry
Abstract Nanocomposites of low‐density polyethylene (LDPE)/ethyl vinyl acetate (EVA)/poly(chloroprene) rubber (PCR) blends and multiple walled carbon nanotubes (MWNT) were prepared in different compositions by melt mixing. The nanocomposites were subjected to different radiation doses and efficacy of radiation crosslinking and physic‐mechanical characteristics were analyzed in detail. Gel content and crosslinking density increased with dose and with the MWNT fraction in the nanocomposites. The elastic modulus of the nanocomposite increased, while elongation at break exhibited downward trend with radiation dose. Micromechanical modeling of elastic modulus indicated presence of agglomeration in the matrix. Bulk density of the nanocomposites increased with the addition of MWNT while the melt flow index of the nanocomposites decreased sharply. DSC, XRD and TGA investigations revealed the peculiarity of the MWNT led nucleation in LDPE/EVA/PCR/MWNT nanocomposites. POLYM. COMPOS., 2011. © 2011 Society of Plastics Engineers