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Investigation on the dynamic melt rheological properties of polypropylene/wood flour composites
Author(s) -
Azizi H.,
Ghasemi I.
Publication year - 2009
Publication title -
polymer composites
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.577
H-Index - 82
eISSN - 1548-0569
pISSN - 0272-8397
DOI - 10.1002/pc.20573
Subject(s) - materials science , dynamic mechanical analysis , composite material , dynamic modulus , rheology , rheometer , polypropylene , modulus , wood flour , dissipation factor , viscosity , composite number , polymer , optoelectronics , dielectric
The rheological behavior of polypropylene/wood flour (WF) composite was investigated at constant temperature over a wide range of frequencies using a mechanical compact rheometer operated in the dynamic mode. The effect of WF content, particle size, and coupling agent on melt rheological properties were investigated. The melt rheological data in terms of complex viscosity (η*), storage modulus ( G ′), loss modulus ( G ″), and loss tangent (tan δ) were studied and compared for different samples. It was found that complex viscosity increases with increasing wood content and coupling agent. Compatibilization using coupling agent increased both storage modulus and loss modulus, but the variation of storage modulus is more. By increasing wood content storage modulus increases. Complex viscosity, storage modulus, and loss modulus showed a minimum value by increasing of wood particle size. Tan δ decreases with increasing of wood content. Cole–Cole plot indicated that relaxation process changes with addition WF, coupling agent, and using different mesh size of wood. The Han plots revealed the sensitivity of rheological properties with composition at constant temperature. POLYM. COMPOS., 2009. © 2008 Society of Plastics Engineers