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Surface modification of bagasse fibers by silane coupling agents through microwave oven and its effects on physical, mechanical, and rheological properties of PP bagasse fiber composite
Author(s) -
Hashemi S.A.,
Arabi H.,
Mirzaeyan N.
Publication year - 2007
Publication title -
polymer composites
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.577
H-Index - 82
eISSN - 1548-0569
pISSN - 0272-8397
DOI - 10.1002/pc.20398
Subject(s) - materials science , composite material , ultimate tensile strength , fiber , polypropylene , composite number , surface modification , scanning electron microscope , bagasse , izod impact strength test , rheology , viscosity , chemical engineering , ecology , engineering , biology
Abstract Polypropylene/bagasse fiber composites were prepared by compounding polypropylene (PP) with bagasse fibers as reinforcing filler. Surfaces of fibers were modified through the use of silane coupling agents (Vinyltrimethoxysilane and γ‐Glycidoxypropyltrimethoxysilane). The fiber coating was performed by mixing of silane with fibers and cured through microwave oven in presence of catalyst. It was found that modification of surface fiber will change the physical, mechanical, morphological, and rheological properties of composite. It was observed from scanning electron microscopy that fiber adhesion to matrix has been improved and so as dispersion. Addition of fibers increases the melt viscosity in unmodified fibers but reduced the melt viscosity for modified fibers and even the viscosity is lower at higher loading compared with unmodified fibers. The tensile strength and tensile modulus increased in modified fibers compared with the unmodified on the same loading, but elongation at break decreased. The effect of coupling agent on properties of filled PP depend on the content of coupling agents and optimum amount was achieve through measurement of water absorption. Two types of coupling agents were used, one as A‐171 [CH 2 CHSi (OCH 3 ) 3 ] and second one as A‐187 [CH 2 OCHCH 2 O (CH 2 ) 3 Si(OCH 3 )], the first one shows better adhesion to the fibers and improvements in mechanical properties are much better compared with the second one. POLYM. COMPOS., 28:713–721, 2007. © 2007 Society of Plastics Engineers