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Epoxy/POSS organic–inorganic hybrids: Viscoelastic, mechanical properties and micromorphologies
Author(s) -
Zhang Zengping,
Liang Guozheng,
Wang Jieliang,
Ren Penggang
Publication year - 2007
Publication title -
polymer composites
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.577
H-Index - 82
eISSN - 1548-0569
pISSN - 0272-8397
DOI - 10.1002/pc.20281
Subject(s) - materials science , silsesquioxane , epoxy , glass transition , composite material , curing (chemistry) , dynamic mechanical analysis , viscoelasticity , flexural strength , scanning electron microscope , flexural modulus , polymer
A series of epoxy resin (EP)/octa(aminpropyl)silsesquioxane (POSS‐NH 2 ) organic–inorganic hybrid composites (EP/POSS‐NH 2 100/0, 95/5, 90/10, and 80/20 wt/wt) were prepared by melt casting and then curing. Viscoelastic and mechanical properties of these composites were studied by dynamic mechanical analysis and mechanical testing, respectively. Scanning electron microscopy was used to study of the micromorphologies of the composites and to elucidate the toughening mechanisms of POSS‐NH 2 . POSS units incorporated into the epoxy network showed good compatibility with the resin matrix. Phase separation was not observed even at high POSS content (20 wt%). Incorporation of POSS macromer into the epoxy network after curing increased the glass transition temperature, slightly narrowed the temperature range widths of the glass transition, and lowered the intensities of their loss moduli peaks of the resultant composites. The glass transition temperature of EP/POSS‐NH 2 composites increased significantly with increasing POSS content at lower POSS content (<10 wt%), while increased slightly at higher POSS content. Both impact and flexural strengths of the hybrids reached their optimum values when 10 wt% content of POSS was introduced. POLYM. COMPOS., 28:175–179, 2007. © 2007 Society of Plastics Engineers.