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Interface modification and characterization in linear low‐density polyethylene highly loaded with aluminium hydroxide
Author(s) -
Wang Genlin,
Jiang Pingkai,
Zhu Zikang
Publication year - 2002
Publication title -
polymer composites
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.577
H-Index - 82
eISSN - 1548-0569
pISSN - 0272-8397
DOI - 10.1002/pc.10469
Subject(s) - materials science , polyethylene , linear low density polyethylene , composite material , ultimate tensile strength , composite number , ductility (earth science) , aluminium , silane , limiting oxygen index , toughness , polymer , low density polyethylene , hydroxide , aluminium hydroxide , chemical engineering , creep , pyrolysis , char , engineering
Fire‐retardant linear low‐density polyethylene (LLDPE) composites were prepared by combining this polymer with uncoated and surface treated forms of aluminum hydroxide (Al(OH) 3 ). The poor toughness and ductility of polyethylene highly filled with Al(OH) 3 can be significantly improved by addition of a small amount of silicon oil. It is found that silicon oil improves elongation at break of the composite remarkably, but this is accompanied by the deterioration of tensile strength. Silane crosslinked polyethylene substituting for polyethylene as the matrix in Al(OH) 3 ‐filled polyethylene improves the tensile strength of the composite. Fractured surface analysis and limiting oxygen index (LOI) of the composites were also studied. Possible mechanisms accounting for these effects are discussed.