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Rheological behavior of low molecular weight polystyrene composites containing monodisperse crosslinked polystyrene beads
Author(s) -
Park M.,
Salovey R.
Publication year - 1999
Publication title -
polymer composites
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.577
H-Index - 82
eISSN - 1548-0569
pISSN - 0272-8397
DOI - 10.1002/pc.10377
Subject(s) - materials science , polystyrene , composite material , rheology , dispersity , composite number , dispersion (optics) , polymer , rheometry , rheometer , polymer chemistry , physics , optics
Steady shear viscosities and dynamic moduli of polymer composites, consisting of crosslinked polystyrene beads and low molecular weight polystyrene matrix, were measured in a cone‐and‐plate rheometer at different temperatures. Viscosities and dynamic moduli were found to be very sensitive to filler loading and measurement temperature. Steady shear viscosities of 30% and 40% loaded low molecular polystyrene composites showed a power‐law behavior over the entire range of shear rates. Storage and loss moduli were initially linear with frequency on double logarithmic plots, with limiting slopes of 0.3 and 0.1. At high concentration of filler particles, they showed a flat plateau at low frequencies, indicating that these systems exhibit a yield behavior. A 20% PS composite loaded with beads of high crosslink densities resulted in poor dispersion of beads as a result of poor dispersion of particles. PS beads 1.16 μm in diameter showed a higher viscosity. It is due to the apparent increase in loading resulting from broken particles. At low measurement temperature, filler effects were suppressed by high viscosity matrix and showed a similar rheological behavior to high molecular weight by PS matrix. We suggest that rheological behavior reflects the state of dispersion of beads in the matrix.