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Stiffness and toughness of polypropylene/glass bead composites
Author(s) -
Kwok K. W.,
Gao Z. M.,
Choy C. L.,
Zhu X. G.
Publication year - 2003
Publication title -
polymer composites
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.577
H-Index - 82
eISSN - 1548-0569
pISSN - 0272-8397
DOI - 10.1002/pc.10005
Subject(s) - materials science , composite material , bead , ultimate tensile strength , composite number , polypropylene , toughness , volume fraction , izod impact strength test , coupling (piping) , modulus , stiffness , glass fiber
The effects of coupling effect, particle diameter ( d ), volume fraction ( V b ) and size distribution (σ) of glass beads on the impact strength and tensile modulus of polypropylene (PP)/glass bead composites have been investigated. The toughness and stiffness of the composite can be simultanously enhanced by using a titanate coupling agent, which gives rise to a moderate interfacial adhesion (characterized by an interaction parameter B ∼ 1) between the glass beads and the matrix. With the addition of this coupling agent, the impact strength of the PP/glass bead composite with d = 2.7 μm and σ = 1.85 increases about 4.5 times as V b increases from 0 to 0.25, while the tensile modulus remains roughly unchanged. For the composites with larger d and narrower size distribution, the impact strength increases only slightly with increasing V b . The combined effect of d , V b and size distribution of the glass beads are described by using a single parameter, the average matrix ligament thickness T . Unlike rubber‐modified polymers, the impact strength of PP/glass bead composites does not follow a master curve when plotted against T .