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Conductivity enhancement in raw polypyrrole and polypyrrole nanoparticle dispersions
Author(s) -
Pomposo JoséAdolfo,
Ochoteco Estibalitz,
Pozo Cristina,
Carrasco PedroMaria,
Grande HansJürgen,
Rodríguez FranciscoJavier
Publication year - 2006
Publication title -
polymers for advanced technologies
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.61
H-Index - 90
eISSN - 1099-1581
pISSN - 1042-7147
DOI - 10.1002/pat.692
Subject(s) - polypyrrole , materials science , polymerization , conductivity , raw material , chemical engineering , yield (engineering) , nanoparticle , particle size , electrical resistivity and conductivity , pyrrole , particle (ecology) , composite material , nanotechnology , polymer , organic chemistry , chemistry , engineering , oceanography , electrical engineering , geology
For certain commercial applications of polypyrrole (PPy), an enhancement of the electrical conductivity of the material is the key to industrial success. In this paper it will be shown that raw PPy with high conductivity (>150 S/cm) can be obtained in very good yield (>90%) by appropriate selection of both bi‐functional additives and reaction conditions which increase the oxidative polymerization rate of pyrrole. The presence of new active centers for the polymerization is demonstrated by UV measurements. In addition, raw PPy synthesized according to the improved method of synthesis shows good stability of the conductivity upon aging at high temperature (150°C) in air. Finally, new PPy dispersions are reported with an average particle size of 67 nm obtained by sonochemical synthesis that can be incorporated into conventional plastic paints for direct metallization of plastics. The conductivity of the new metallization paint developed was 0.4 S/cm with a PPy content of 10 wt%. Copyright © 2006 John Wiley & Sons, Ltd.