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Removal of dyes from water by conducting polymeric adsorbent
Author(s) -
Chowdhury A.N.,
Jesmeen S. R.,
Hossain M. M.
Publication year - 2004
Publication title -
polymers for advanced technologies
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.61
H-Index - 90
eISSN - 1099-1581
pISSN - 1042-7147
DOI - 10.1002/pat.521
Subject(s) - adsorption , polyaniline , cationic polymerization , methylene blue , aqueous solution , acid dye , materials science , langmuir adsorption model , langmuir , chemical engineering , selectivity , selective adsorption , base (topology) , polymer , polymer chemistry , inorganic chemistry , chemistry , organic chemistry , composite material , dyeing , catalysis , polymerization , photocatalysis , mathematical analysis , mathematics , engineering
Chemically synthesized conducting polyaniline (PANI) was investigated as adsorbent for its possible application in the removal of organic dyes, such as methylene blue (MB) and procion red (PR) from their aqueous solution. PANI adsorbent behaves as a charged surface upon post‐synthesis treatment of the polymer with acid and base. The adsorbent thus treated shows a high selectivity for the removal of dyes in the adsorption process. The Langmuir adsorption isotherm was used to represent the experimental adsorption data. The cationic dye, MB can be preferentially removed by the base‐treated PANI while the anionic dye, PR is predominately removed by the acid‐treated one. These observations were further evidenced from the measurements of molar conductance and pH of the dye solutions employed for adsorption. The finding can be explained considering the electrostatic nature of adsorption coupled with the morphology of the PANI surface thus treated. Copyright © 2004 John Wiley & Sons, Ltd.