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Thermal and mechanical properties of LDPE by the effects of organic peroxides
Author(s) -
Sirin Kamil,
Cengel Ömer,
Canli Murat
Publication year - 2017
Publication title -
polymers for advanced technologies
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.61
H-Index - 90
eISSN - 1099-1581
pISSN - 1042-7147
DOI - 10.1002/pat.3992
Subject(s) - low density polyethylene , materials science , peroxide , melt flow index , ultimate tensile strength , thermogravimetric analysis , elongation , scanning electron microscope , polyethylene , composite material , organic peroxide , yield (engineering) , polymer chemistry , organic chemistry , polymer , chemistry , copolymer
In this study, the effect of different organic peroxides on different types of low‐density polyethylene (LDPE) was investigated. LDPE products like F2‐21T, F5‐21T, and I22‐19T were mixed in different proportions with dialkyl peroxide, dibenzoyl peroxide, and dilauroyl peroxide. Melt flow rates, mechanical properties (tensile strength at yield, tensile strength at break, elongation at break, and stress‐strain effect), thermal analysis (differential scanning calorimetric and thermogravimetric analysis), and scanning electron microscopy images of the prepared mixtures were examined. Cross‐linking occurred in the structure of LDPE types having different molecular weight distribution by the addition of even small amounts of peroxide (e.g. 0–0.12 wt%). Copyright © 2017 John Wiley & Sons, Ltd.