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Modern solid state NMR techniques and concepts in structural studies of synthetic polymers
Author(s) -
Kaźmierski S.,
Pawlak T.,
Jeziorna A.,
Potrzebowski M. J.
Publication year - 2016
Publication title -
polymers for advanced technologies
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.61
H-Index - 90
eISSN - 1099-1581
pISSN - 1042-7147
DOI - 10.1002/pat.3780
Subject(s) - magic angle spinning , solid state nuclear magnetic resonance , materials science , polymer , spinning , solid state , nuclear magnetic resonance spectroscopy , nuclear magnetic resonance , chemistry , physics , polymer chemistry , composite material
In this mini‐review, we present the solid state nuclear magnetic resonance (NMR) methods which trace the new tendency in structural studies of synthetic polymers. The review is organized into three sections. In the first part, short theoretical background and introduction to very fast magic angle spinning NMR technique with sample rotation 60 kHz are shown. The second part presents method for enhancing the sensitivity of NMR experiments by application of dynamic nuclear polarization magic angle spinning technique. In the third section, the power of the NMR crystallography approach which can be used for fine refinement of polymers structure on the atomic level is discussed. Copyright © 2016 John Wiley & Sons, Ltd.