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Staudinger–Vilarassa reaction versus Huisgen reaction for the control of surface hydrophobicity and water adhesion
Author(s) -
Godeau Guilhem,
N'Na Jessica,
El Kout Emna,
Ben Trad Rawia,
Darmanin Thierry,
El Kateb Mejda,
Beji Mohammed,
Guittard Frédéric
Publication year - 2016
Publication title -
polymers for advanced technologies
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.61
H-Index - 90
eISSN - 1099-1581
pISSN - 1042-7147
DOI - 10.1002/pat.3759
Subject(s) - alkyl , surface modification , aryl , monomer , click chemistry , materials science , adhesion , surface (topology) , combinatorial chemistry , polymer chemistry , chemistry , nanotechnology , organic chemistry , polymer , mathematics , geometry
Surface modifications are keys for a great number of applications. In order to perfectly control the surface properties, it is important to control the modification pathways. Two general pathways can be described in order to introduce modification on surfaces: the post‐ strategies and the ante‐ strategies. In this work, we focus on the comparison between the Huisgen and the Staudinger–Vilarrasa reaction for both post‐ surface and ante ‐surface modifications. Here, we focused on the possibility to use both two reactions to obtain superhydrophobic and oleophobic properties. This work includes monomer synthesis, surface modifications with alkyl, aryl or perfluoroalkyl chain. Copyright © 2016 John Wiley & Sons, Ltd.