Low glass transition temperature poly(ionic liquid) prepared from a new quaternary ammonium cationic monomer | Zendy

He Hongkun | Zendy; Chung Heesung | Zendy; Roth Elliot | Zendy; Luebke David | Zendy; Hopkinson David | Zendy; Nulwala Hunaid | Zendy; Matyjaszewski Krzysztof | Zendy

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Low glass transition temperature poly(ionic liquid) prepared from a new quaternary ammonium cationic monomer

Author(s) -

He Hongkun,

Chung Heesung,

Roth Elliot,

Luebke David,

Hopkinson David,

Nulwala Hunaid,

Matyjaszewski Krzysztof

Publication year - 2015

Publication title -

polymers for advanced technologies

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.61

H-Index - 90

eISSN - 1099-1581

pISSN - 1042-7147

DOI - 10.1002/pat.3529

Subject(s) - ionic liquid , cationic polymerization , atom transfer radical polymerization , differential scanning calorimetry , glass transition , materials science , polymer chemistry , monomer , copolymer , polymerization , ammonium , polymer , organic chemistry , chemistry , catalysis , composite material , physics , thermodynamics

Well‐defined poly(ionic liquid)s (PILs) were synthesized by normal and activators regenerated by electron transfer atom transfer radical polymerization (ATRP) using a new ionic liquid monomer, N ‐(4‐vinylbenzyl)‐tris[2‐(2‐methoxyethoxy)ethyl]ammonium bis(trifluoromethylsulfonyl)imide (VBTA + Tf 2 N − ). ATRP was also used for the preparation of PIL block copolymers using di‐functional PIL macroinitiators. Differential scanning calorimetry measurement showed the polyVBTA + Tf 2 N − had a rather low glass transition temperature of −43°C. Copyright © 2015 John Wiley & Sons, Ltd.

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