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Compatibilized poly(ether imide)/LCP blends: drawing ability and mechanical properties of the ribbons
Author(s) -
Vallejo F. J.,
Bastida S.,
Eguiazábal J. I.,
Nazábal J.
Publication year - 2002
Publication title -
polymers for advanced technologies
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.61
H-Index - 90
eISSN - 1099-1581
pISSN - 1042-7147
DOI - 10.1002/pat.217
Subject(s) - materials science , ultimate tensile strength , composite material , compatibilization , young's modulus , anisotropy , modulus , ductility (earth science) , imide , polymer blend , polymer , polymer chemistry , copolymer , creep , physics , quantum mechanics
The effects of the addition of polyarylate (PAr) on the drawing ability of poly(ether imide) (PEI)/Rodrun liquid‐crystalline 5000 (Ro LC5000) (Ro) blends and on the mechanical properties of their ribbons were studied. The compatibilizing effect of the PAr led to an increase in the drawing ability of the blends, as seen by the fact that the maximum Ro content compatible with the drawing process increased from 15 to 30%. This may lead to new applications in the field of gas barrier materials. The presence of PAr also led to an increase in the adhesion between the two phases of the blends and consequent improved ductility. However, the very high modulus of elasticity and tensile strength in the direction of orientation (up to three‐fold those of the matrix) due to the less developed fibrillation were smaller than the corresponding values before compatibilization. These very large modulus of elasticity and tensile strength values and those perpendicular to the direction of orientation, which were similar to those of the matrix, led to a high anisotropy in the extruded ribbons that increased with the draw ratio (DR) and the Ro contents. The high mechanical properties of the ribbons may be used and the anisotropy diminished by layering the ribbons in, and perpendicular to, the direction of orientation, according to the expected external load. Copyright © 2002 John Wiley & Sons, Ltd.