Fast and reversible CO 2  quartz crystal microbalance response of vinylimidazolium‐based poly(ionic liquid)s | Zendy

Mineo Placido G. | Zendy; Livoti Letizia | Zendy; Lo Schiavo Sandra | Zendy; Cardiano Paola | Zendy

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Fast and reversible CO 2 quartz crystal microbalance response of vinylimidazolium‐based poly(ionic liquid)s

Author(s) -

Mineo Placido G.,

Livoti Letizia,

Lo Schiavo Sandra,

Cardiano Paola

Publication year - 2012

Publication title -

polymers for advanced technologies

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.61

H-Index - 90

eISSN - 1099-1581

pISSN - 1042-7147

DOI - 10.1002/pat.2076

Subject(s) - quartz crystal microbalance , ionic liquid , sorption , materials science , desorption , imide , ion , ionic bonding , chemical engineering , analytical chemistry (journal) , inorganic chemistry , polymer chemistry , chemistry , adsorption , organic chemistry , catalysis , engineering

A series of poly(ionic liquid)s (pILs) based on the 1‐vinyl‐3‐hexylimidazolium polymerizable cation and on the bis(trifluoromethylsulfonyl)imide, nonafluoro‐1‐butanesulfonate, dodecylbenzenesulfonate, heptadecafluorooctanesulfonate, and 4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11‐heptadecafluoroundecanoate anions have been synthesized and characterized. Their sorption/desorption response towards CO 2 has been tested through quartz crystal microbalance investigations. The obtained results show that all of the pILs here reported are featured by peculiar CO 2 sorption properties as they display fast and linear response, reversibility without any memory effect, and reproducibility, suggesting that anion plays a key role in determining sensitivity. Copyright © 2011 John Wiley & Sons, Ltd.

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