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Oxygenation of 3‐pentanol to 3‐pentanone catalyzed by polymer–platinum complex
Author(s) -
Yang XiaoTun,
Yin ShuPu,
Huang MeiYu,
Jiang YingYan
Publication year - 1994
Publication title -
polymers for advanced technologies
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.61
H-Index - 90
eISSN - 1099-1581
pISSN - 1042-7147
DOI - 10.1002/pat.1994.220050926
Subject(s) - platinum , catalysis , polymer , oxygenation , solvent , yield (engineering) , materials science , oxygen , inorganic polymer , atmospheric pressure , inorganic chemistry , polymer chemistry , photochemistry , chemical engineering , chemistry , organic chemistry , metallurgy , composite material , ecology , oceanography , engineering , biology , geology
A new inorganic polymer–platinum complex, silicasupported polysilazane–platinum complex, has been prepared and found to be capable of catalyzing the oxygenation of 3‐pentanol to 3‐pentanone in 100% yield at moderate temperature and under atmospheric oxygen pressure. Water is the best solvent for this reaction. This inorganic polymer complex is very stable in the reaction and can be reused several times without any appreciable change in catalytic activity.