Sulfur‐containing polymers by the reaction of diphenyl sulfide with sulfur chlorides | Zendy

Miyatake Kenji | Zendy; Jikei Mitsutoshi | Zendy; Yamamoto Kimihisa | Zendy; Nishide Hiroyuki | Zendy; Tsuchida Eishun | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Sulfur‐containing polymers by the reaction of diphenyl sulfide with sulfur chlorides

Author(s) -

Miyatake Kenji,

Jikei Mitsutoshi,

Yamamoto Kimihisa,

Nishide Hiroyuki,

Tsuchida Eishun

Publication year - 1992

Publication title -

polymers for advanced technologies

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.61

H-Index - 90

eISSN - 1099-1581

pISSN - 1042-7147

DOI - 10.1002/pat.1992.220030706

Subject(s) - sulfur , sulfide , materials science , polymer , organic chemistry , hydrogen sulfide , chemistry , metallurgy , composite material

The electrophilic reaction of sulfur dichloride with diphenyl sulfide proceeds efficiently at room temperature to yield oligo(phenylene sulfide) in the presence of a catalytic amount of Fe powder. Sulfur dichloride shows higher reactivity than sulfur monochloride. The reaction is promoted through the activation of sulfur dichloride by Fe powder. The polymeric product contains a linear structure linked by disulfide and sulfide bonds.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research