Electro‐oxidative polymerization of 1,3‐Cyclohexadiene | Zendy

Yamamoto Kimihisa | Zendy; Asada Toshio | Zendy; Nishide Hiroyuki | Zendy; Tsuchida Eishun | Zendy

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Electro‐oxidative polymerization of 1,3‐Cyclohexadiene

Author(s) -

Yamamoto Kimihisa,

Asada Toshio,

Nishide Hiroyuki,

Tsuchida Eishun

Publication year - 1990

Publication title -

polymers for advanced technologies

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.61

H-Index - 90

eISSN - 1099-1581

pISSN - 1042-7147

DOI - 10.1002/pat.1990.220010303

Subject(s) - materials science , polymerization , polymer , phenylene , polymer chemistry , alkene , photochemistry , organic chemistry , chemistry , catalysis , composite material

1,3‐Cyclohexadiene is electropolymerized at a lower applied potential, compared with the polymerization of other alkene compounds, to give insoluble polymer film on an electrode. The formed polymer contains a phenylene repeated unit, which is confirmed by IR, 1 H‐ and 13 C‐NMR spectroscopy. Poly(cyclohexene) produced by the electropolymerization is partially aromatized by the oxidation to form a phenylene unit which is accompanied by an elimination of a proton.

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