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In situ fibrillation of polyamide 6 in isotactic polypropylene occurring in the laminating‐multiplying die
Author(s) -
Shen Jiabin,
Wang Ming,
Li Jiang,
Guo Shaoyun
Publication year - 2011
Publication title -
polymers for advanced technologies
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.61
H-Index - 90
eISSN - 1099-1581
pISSN - 1042-7147
DOI - 10.1002/pat.1525
Subject(s) - materials science , tacticity , polyamide , composite material , nucleation , ultimate tensile strength , rheology , polypropylene , morphology (biology) , phase (matter) , extrusion , viscoelasticity , elongation , polymer , polymerization , biology , genetics , chemistry , organic chemistry
The polyamide 6 (PA6)/isotactic polypropylene (iPP) in situ fibrillation composites are prepared by a novel extrusion die with an assembly of laminating‐multiplying elements (LMEs). The scanning electron micrographs illustrate that the dividing‐multiplying processes in LMEs elongate, break, and stabilize the dispersed PA6 phase in the iPP matrix along the flowing direction (FD). The morphology development of PA6 with different LME numbers greatly affects the rheological properties, crystalline behaviors, and mechanical properties. The dynamic rheological test performed at 195°C shows that the increased spatial restriction of the high‐aspect‐ratio PA6 particles increases the viscoelastic moduli, complex viscosity, and relaxation time. The crystalline analysis reveals that the heterogeneous nucleation becomes predominant and the transcrystalline morphology is observed in those samples produced by more LMEs. The tensile tests indicate that both, breaking strength and elongation, enhanced simultaneously because of the fibrillation of dispersed phase and the improvement in interfacial adhesion between the fibers and the matrix. Copyright © 2009 John Wiley & Sons, Ltd.