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Aqueous catalysis by novel macromolecule metal complexes with molecular recognition abilities
Author(s) -
Karakhanov Edward A.,
Kardasheva Yulia S.,
Maximov Anton L.,
Runova Elena A.,
Buchneva Tatyana A.,
Gaevskiy Mihail A.,
Zhuchkova Anna Ya.,
Filippova Tatyana Yu.
Publication year - 2001
Publication title -
polymers for advanced technologies
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.61
H-Index - 90
eISSN - 1099-1581
pISSN - 1042-7147
DOI - 10.1002/pat.140
Subject(s) - catalysis , catechol , hydroformylation , aqueous solution , phenol , chemistry , acetylacetone , organic chemistry , nitrile , metal , hydroxylation , polymer chemistry , macromolecule , combinatorial chemistry , rhodium , biochemistry , enzyme
A number of water‐soluble macromolecular metal complexes on the basis of polyethers, β‐cyclodextrins, calix[4] and calix[6]arenes functionalized by oligoethylene oxide blocks, catechol, ethylendiamine, acetylacetone, 2,2′‐dipiridyl, phosphines and nitrile containing groups have been developed. Complexes showed high catalytic activity in aqueous hydroformylation, biphasic Wacker‐type oxidation of various higher olefines, alkane oxidation, hydroxylation of benzene and phenol. These catalysts can be multiply reused. The application of host compounds results the extremely selectivities. Copyright © 2001 John Wiley & Sons, Ltd.