Total Synthesis of Resveratrone and  iso ‐Resveratrone | Zendy

Fritsch Stefan | Zendy; Aldemir Nazli | Zendy; Balszuweit Jan | Zendy; Bojaryn Kevin | Zendy; Voskuhl Jens | Zendy; Hirschhäuser Christoph | Zendy

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Total Synthesis of Resveratrone and iso ‐Resveratrone

Author(s) -

Fritsch Stefan,

Aldemir Nazli,

Balszuweit Jan,

Bojaryn Kevin,

Voskuhl Jens,

Hirschhäuser Christoph

Publication year - 2022

Publication title -

chemistryopen

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.644

H-Index - 29

ISSN - 2191-1363

DOI - 10.1002/open.202200098

Subject(s) - epoxide , azide , derivative (finance) , chemistry , combinatorial chemistry , total synthesis , absorption (acoustics) , organic chemistry , materials science , catalysis , financial economics , economics , composite material

The first total synthesis of resveratrone and iso ‐resveratrone based on an epoxide olefination approach is described. The pivotal reaction proceeds by insertion of the lithiated epoxide into a boronic ester and subsequent syn ‐elimination. Resveratrone has been described to have remarkable photophysical properties, including two‐photon absorption. Therefore, an azide derivative has been prepared to allow for use as a biological label.

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