Open AccessProtonated Ethylene Carbonate: A Highly Resonance‐Stabilized Cation
Author(s) -
Beck Stefanie,
Jessen Christoph,
Kornath Andreas J.
Publication year - 2021
Publication title -
chemistryopen
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.644
H-Index - 29
ISSN - 2191-1363
DOI - 10.1002/open.202100229
Subject(s) - natural bond orbital , delocalized electron , chemistry , protonation , raman spectroscopy , ethylene carbonate , moiety , ethylene , carbonate , lewis acids and bases , infrared spectroscopy , crystallography , single crystal , inorganic chemistry , density functional theory , stereochemistry , ion , computational chemistry , organic chemistry , physics , electrode , electrolyte , catalysis , optics
Salts containing the monoprotonated ethylene carbonate species of were obtained by reacting it with the superacidic systems X F/ M F 5 ( X =H, D; M =Sb, As). The salts in terms of [C 3 H 5 O 3 ] + [SbF 6 ] − , [C 3 H 5 O 3 ] + [AsF 6 ] − and [C 3 H 4 DO 3 ] + [AsF 6 ] − were characterized by low‐temperature infrared and Raman spectroscopy. In order to generate the diprotonated species of ethylene carbonate, an excess of Lewis acid was used. However, this only led to the formation of [C 3 H 5 O 3 ] + [Sb 2 F 11 ] − , which was characterized by a single‐crystal X‐ray structure analysis. Quantum chemical calculations on the B3LYP/aug‐cc‐PVTZ level of theory were carried out for the [C 3 H 5 O 3 ] + cation and the results were compared with the experimental data. A Natural Bond Orbital (NBO) analysis revealed sp 2 hybridization of each atom belonging to the CO 3 moiety, thus containing a remarkably delocalized 6π‐electron system. The delocalization is confirmed by a 13 C NMR‐spectroscopic study of [C 3 H 5 O 3 ] + [SbF 6 ] − .