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We designed multiblock amphiphiles  AmF  and  AmH , which consist of perfluorinated and non‐fluorinated hydrophobic units, respectively. Absorption spectroscopy revealed that both amphiphiles are molecularly dispersed in organic solvent, while they form aggregates under aqueous conditions. Furthermore, we investigated whether  AmF  and  AmH  can be incorporated into DOPC lipid bilayer membranes, and found that the maximum concentration of  AmF  that can be incorporated into DOPC lipid bilayer membranes is 43 times higher than that of  AmH .

Aromatic Fluorination of Multiblock Amphiphile Enhances Its Incorporation into Lipid Bilayer Membranes