Open AccessSterically Demanding Unsymmetrical Diaryl‐λ 3 ‐iodanes for Electrophilic Pentafluorophenylation and an Approach to α‐Pentafluorophenyl Carbonyl Compounds with an All‐Carbon Stereocenter
Author(s) -
Matsuzaki Kohei,
Okuyama Kenta,
Tokunaga Etsuko,
Shiro Motoo,
Shibata Norio
Publication year - 2014
Publication title -
chemistryopen
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.644
H-Index - 29
ISSN - 2191-1363
DOI - 10.1002/open.201402098
Subject(s) - halogen , electrophile , stereocenter , fluorine , steric effects , chemistry , reagent , iodine , cover (algebra) , organic chemistry , catalysis , engineering , enantioselective synthesis , mechanical engineering , alkyl
Invited for this months cover is the group of Professor Norio Shibata. The cover picture shows the Japanese painting “Genshi‐Chi” (“Primitive Land”) by Mami Shibata: our state‐of‐the‐art reagent for pentafluorophenylation is realized by the cooperation of the halogens fluorine and iodine—elements from the primitive Earth. For more details, see the Communication on 10.1002/open.201402045/full (( p. 233 ff.))