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Rearrangements accompanying the fragmentation of ionized 1‐phenylalkan‐1‐ols
Author(s) -
Budzikiewicz H.,
Drabner G.,
Hammes Ch.
Publication year - 1993
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210281107
Subject(s) - fragmentation (computing) , labelling , collision , chemistry , ionization , computer science , ion , organic chemistry , biochemistry , computer security , operating system
Some aspects of the fragmentation sequence of 1‐phenylalkan‐1‐ols (C 6 H 5 CH(OH)R), which consists of the loss of R˙ followed by the elimination of CO and subsequently of H 2 , are discussed. Labelling studies and collision activation data of reference compounds allow a mechanism to be proposed for this rearrangement.
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